The Measurement of Solute Diffusion Coefficients in Dilute Liquid Alloys: The Influence of Unit Gravity and G ‐Jitter on Buoyancy Convection

A bstract : Liquid diffusion experiments conducted on the MIR space station using the Canadian Space Agency QUELD II processing facility and the microgravity isolation mount (MIM) showed that g ‐jitter significantly increased the measured solute diffusion coefficients. In some experiments, milli‐ g forced vibration was superimposed on the sample when isolated from the ambient g ‐jitter; this resulted in markedly increased solute transport. To further explore the effects arising in these long capillary diffusion couples from the absence of unit‐gravity and the presence of the forced g ‐jitter, the effects of a 1 milli‐ g forcing vibration on the mass transport in a 1.5 mm diameter long capillary diffusion couple have been simulated. In addition, to increase understanding of the role of unit gravity in determining the extent to which gravity can influence measured diffusion coefficient values, comparative experiments involving gold, silver, and antimony diffusing in liquid lead have been carried out using a similar QUELD II facility to that employed in the QUELD II/MIM/MIR campaign but under terrestrial conditions. It was found that buoyancy‐driven convection may still persist in the liquid even when conditions are arranged for a continuously decreasing density gradient up the axis of a vertical long capillary diffusion couple due to the presence of small radial temperature gradients.