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THE PHOTOCHEMISTRY OF THE AZOALKANES †
Author(s) -
COLLIER SUSAN S.,
SLATER DAVID H.,
CALVERT JACK G.
Publication year - 1968
Publication title -
photochemistry and photobiology
Language(s) - Spanish
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1968.tb08059.x
Subject(s) - photodissociation , chemistry , gas phase , photochemistry
Abstract— New evidence is presented to help define the nature of the excited states and the primary processes involved in the gas phase photolysis of the azoalkanes. Kinetic data derived from direct and sensitized photolysis of azoisobutane are presented. The present data and other published data are considered in the formulation of the suggested mechanism. RESUMEN Se presenta una nuevo evidencia que ayuda a deflnir la naturaleza de los estados excitados y de los procesos primarios que involucran la fotólisis en fase gaseosa de log azoalquenos. Se exponen datos cinéticos obtenidos a partir de la fotólisis directa ya sensitivizada del azoisobutano. Los datos presentes y otros publicados están considerados en laformulación del sugerido mecanismo.