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Structure and Cohesive Energy Density of Fats and Their Sorption by Polymer Films
Author(s) -
ARORA A. P.,
HALEK G. W.
Publication year - 1994
Publication title -
journal of food science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.772
H-Index - 150
eISSN - 1750-3841
pISSN - 0022-1147
DOI - 10.1111/j.1365-2621.1994.tb14707.x
Subject(s) - sorption , polymer , polypropylene , polyethylene , chemistry , palmitic acid , oleic acid , organic chemistry , compatibility (geochemistry) , chemical engineering , fatty acid , materials science , adsorption , composite material , biochemistry , engineering
Polypropylene and polyethylene terephthalate films were immersed in pure triglycerides or fatty acids for a range of times. They were analyzed for the amount sorbed to determine the relative importance of fat chemical configuration and cohesive energy density (CED) on sorption order and amount. Structure affected the order of sorption (palmitic > oleic > linoleic acids or triglycerides) while CED differences and the fatty components determined compatibility. The amount of the CED differences affected the relative solubilities of fatty components in the polymers. The Hildebrand equation for heat of mixing gave values for components in the same order as the experimental results had indicated.

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