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Ψ‐Polyhedral symbols for coordination geometries of lead(II) with a stereochemically active lone pair
Author(s) -
Ng Seik Weng
Publication year - 2021
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s205322962100663x
Subject(s) - lone pair , atom (system on chip) , chemical nomenclature , crystallography , chemistry , stereochemistry , computer science , molecule , organic chemistry , embedded system
Because an IUCr/IUPAC‐designated set of letters/numbers identifies the configuration of the atoms linked to the Pb II atom in its coordination compounds, a Ψ prefix before such as a polyhedral symbol provides useful information when its lone pair is stereochemically active. Such notation is especially relevant when the metal atom is connected to eight or more atoms regardless of whether the lone pair is active or inert. The polyhedral symbols for the crystal structures in some 50 articles published after 2000 are reported here as the original studies did not expressly identify coordination geometries.

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