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Investigation results of microstructure influence on oxidation coefficient during chemical-heat treatment of V–Cr–W–Zr alloy are presented. It is shown that the formation of a high defect structural state in the alloy leads to a twofold increase in the oxidation coefficient and a significant increase in the oxygen concentration. The maximum effects of the microstructure on the oxidation processes are detected at short treatment times.

Influence of V–Cr–W–Zr alloy microstructure on features of oxidation during chemical-heat treatment