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Glycerol carbonate, a value-added derivative of biomass glycerol, has been synthesized by the transesterification of dimethyl carbonate with glycerol using anhydrous sodium silicate (Na 2 SiO 3 ) as highly efficient, green and available solid base catalyst. The yield of glycerol carbonate reached up to 93% in 10 minutes under microwave irradiation. The result of leaching test indicated Na 2 SiO 3  was a well-defined heterogeneous catalyst for the reaction. In addition, Na 2 SiO 3  could be reused in 4 runs without significant loss of its catalytic activity.

Microwave assisted rapid synthesis of glycerol carbonate from glycerol catalyzed by anhydrous sodium silicate