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Hetero‐metallic Lanthanide CPs Involving Sodium: Synthesis, Crystal Structure, and Luminescence Properties
Author(s) -
Nie ZhiWen,
Li ShaSha,
Zeng ChengHui,
Wang Lei,
Li Yuan,
Yin ShunGao,
Zhong ShengLiang
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400202
Subject(s) - monoclinic crystal system , luminescence , lanthanide , crystallography , infrared spectroscopy , fourier transform infrared spectroscopy , metal , crystal structure , materials science , powder diffraction , single crystal , quantum yield , chemistry , inorganic chemistry , organic chemistry , optics , optoelectronics , metallurgy , fluorescence , ion , physics
[TbNa(4‐msal) 4 (phen) 2 ] n ( 1 ) (4‐msal = 4‐methyl salicylic acid), a new hetero‐metallic lanthanide coordination polymer (CP) involving sodium was synthesized. It crystallizes in the monoclinic space group P 2 1 / n , with a = 20.4809(9) Å, b = 9.8183(2) Å, c = 26.1987(11) Å, α = 90.00°, β = 112.922(5)°, γ = 90.00°, V = 4852.2(3) Å 3 , and Z = 4. The complex was characterized by single crystal and powder X‐ray diffraction, elemental analysis (EA), and Fourier transform infrared (FT‐IR) and luminescence spectroscopy. The luminescence properties of a powder sample of 1 were studied at room temperature and the luminescence lifetime and total quantum yield (QY) were determined.
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