Premium
A dmp‐type Microporous Cadmium(II)‐Isonicotinate: Synthesis, Structure and CO 2 Adsorption Property
Author(s) -
Zhang Zhihua
Publication year - 2014
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201400024
Subject(s) - microporous material , cadmium , molecule , adsorption , isonicotinic acid , dimethylacetamide , solvothermal synthesis , materials science , crystallography , polymer chemistry , chemistry , organic chemistry , hydrazide , solvent
Abstract The 4‐connected dmp ‐type cadmium(II)‐isonicotinate framework [Cd(isonic) 2 (H 2 O)] n · n (DMA) ( 1 ) (isonic = isonicotinate, DMA = N , N ′‐dimethylacetamide) was obtained by the solvothermal reactions of Cd(NO 3 ) 2 and isonicotinic acid (Hisonic). Compound 1 features a 3D porous framework with the opened channels occupied by the lattice DMA molecules. Thermal analysis reveals that such framework remains much stable after removal the free DMA molecules. CO 2 adsorption measurement shows that such framework exhibits notable CO 2 adsorption behavior.