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A Novel Two‐Dimensional Cadmium Polymeric Aminonaphthalene Sulfonate and its Application in the Synthesis of CdS Materials
Author(s) -
Mi LiWei,
Han MinLe,
Li DaPeng,
Chen WeiHua,
Zheng Zhi
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700396
Subject(s) - sulfonate , chemistry , sulfonic acid , crystallography , crystal structure , ligand (biochemistry) , polymer chemistry , hydrogen bond , naphthalene , bridging ligand , inorganic chemistry , stereochemistry , molecule , organic chemistry , sodium , biochemistry , receptor
Abstract A new mixed‐ligand complex, [CdL(bipy)(CH 3 OH)(NO 3 )] n ( 1 ), (HL = 4‐amino‐1‐naphthalene sulfonic acid and bipy = 4,4′‐bipyridine) could be achieved by combining d 10 Cd 2+ to HL and bridging ligand 4,4′‐bipy. The structure is characterized by X‐ray single‐crystal diffraction. 4‐amino‐1‐naphthalene sulfonate and 4,4′‐bipyridine act as bridging ligands, linking two adjacent Cd II atom to form a two‐dimensional coordination polymer, respectively. N‐H···O hydrogen‐bonding interaction between these networks to form the face‐to‐face three‐dimensional architecture. By carrying out the reaction of polymeric cadmium naphthalene sulfonate with Na 2 S in the presence of sodium hydroxide, scalelike CdS materials have been obtained. The structure has been characterized by scanning electron microscopy and powder X‐ray diffraction.