Synthesis, Molecular Structure, Optical Properties and Electrical Conductivity of Zwitterionic Ferrocenyldithiophosphonates | Zendy

Karakus Mehmet | Zendy; Aydogdu Yıldırım | Zendy; Celik Omer | Zendy; Kuzucu Veysel | Zendy; Ide Semra | Zendy; HeyHawkins Evamarie | Zendy

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Synthesis, Molecular Structure, Optical Properties and Electrical Conductivity of Zwitterionic Ferrocenyldithiophosphonates

Author(s) -

Karakus Mehmet,

Aydogdu Yıldırım,

Celik Omer,

Kuzucu Veysel,

Ide Semra,

HeyHawkins Evamarie

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600319

Subject(s) - elemental analysis , chemistry , spectroscopy , electrical resistivity and conductivity , mass spectrometry , ethanol , infrared spectroscopy , conductivity , crystallography , nuclear chemistry , stereochemistry , analytical chemistry (journal) , inorganic chemistry , organic chemistry , physics , chromatography , quantum mechanics

Ferrocenyldithiodiphosphetane [FcPS(μ‐S)] 2 [Fc = Fe(η 5 ‐C 5 H 4 )(η 5 ‐C 5 H 5 )] reacts with the aminoethanol derivatives 1‐ethyl‐3‐pyrrolidinol and 2‐(piperazin‐1‐yl)ethanol to give the zwitterionic ( O ‐ethylammonium)ferrocenyldithiophosphonates $\rm [FcP(S)S(\overline{C_{4}H_{7}N}HEt)]$ ( 2 ) and $\rm [FcP(S)S(OC_{2}H_{4}\overline{NHC_{4}H_{8}N}H)]$ ( 3 ), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electrical properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC 2 H 4 NHEt 2 )] ( 1 ) were studied. A molecular structure determination of 1 is also reported.

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