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Synthesis, Molecular Structure, Optical Properties and Electrical Conductivity of Zwitterionic Ferrocenyldithiophosphonates
Author(s) -
Karakus Mehmet,
Aydogdu Yıldırım,
Celik Omer,
Kuzucu Veysel,
Ide Semra,
HeyHawkins Evamarie
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600319
Subject(s) - elemental analysis , chemistry , spectroscopy , electrical resistivity and conductivity , mass spectrometry , ethanol , infrared spectroscopy , conductivity , crystallography , nuclear chemistry , stereochemistry , analytical chemistry (journal) , inorganic chemistry , organic chemistry , physics , chromatography , quantum mechanics
Abstract Ferrocenyldithiodiphosphetane [FcPS(μ‐S)] 2 [Fc = Fe(η 5 ‐C 5 H 4 )(η 5 ‐C 5 H 5 )] reacts with the aminoethanol derivatives 1‐ethyl‐3‐pyrrolidinol and 2‐(piperazin‐1‐yl)ethanol to give the zwitterionic ( O ‐ethylammonium)ferrocenyldithiophosphonates $\rm [FcP(S)S(\overline{C_{4}H_{7}N}HEt)]$ ( 2 ) and $\rm [FcP(S)S(OC_{2}H_{4}\overline{NHC_{4}H_{8}N}H)]$ ( 3 ), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electrical properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC 2 H 4 NHEt 2 )] ( 1 ) were studied. A molecular structure determination of 1 is also reported.