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Complexes of decamethylsilicocene: Cp 2 *Si(CO) and Cp 2 *Si(N 2 )
Author(s) -
Tacke M.,
Klein Ch.,
Stufkens D. J.,
Oskam A.,
Jutzi P.,
Bunte E. A.
Publication year - 1993
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19936190510
Subject(s) - xenon , bar (unit) , nitrogen , chemistry , silicon , infrared , infrared spectroscopy , crystallography , analytical chemistry (journal) , materials science , physics , organic chemistry , optics , meteorology
Abstract The synthesis and IR spectroscopic detection of the monocarbonyl and mononitrogen complex of decamethylsilicocen in liquid xenon (LXe) and liquid nitrogen (LN 2 ) is reported. The reactions were found to be highly incomplete under a few bar of CO or N 2 and reversibel when the pressure is released. Cp 2 *Si(CO) is characterized by three isotopomeres and Cp 2 *Si(N 2 ) was synthesized on two independent routes.