Premium
Some Oxovanadium(IV) Complexes with C 2v Symmetry
Author(s) -
Syamal A.
Publication year - 1970
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19703730212
Subject(s) - symmetry (geometry) , infrared , crystallography , chemistry , nuclear magnetic resonance , stereochemistry , physics , mathematics , quantum mechanics , geometry
Synthesis of few oxovanadium (IV) complexes of C 2v symmetry with low symmetry β‐diketones is described. Magnetic, infrared and electronic spectral studies of the complexes are reported. Splitting of the xy → xz, yz transition is observed at 77°K and is believed to be of vibrational origin.