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Deepening the Valance Band Edges of NiO x Contacts by Alkaline Earth Metal Doping for Efficient Perovskite Photovoltaics with High Open‐Circuit Voltage
Author(s) -
Ge Bing,
Qiao Hong Wei,
Lin Ze Qing,
Zhou Zi Ren,
Chen Ai Ping,
Yang Shuang,
Hou Yu,
Yang Hua Gui
Publication year - 2019
Publication title -
solar rrl
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.544
H-Index - 37
ISSN - 2367-198X
DOI - 10.1002/solr.201970066
Subject(s) - doping , non blocking i/o , open circuit voltage , materials science , alkaline earth metal , energy conversion efficiency , perovskite (structure) , photovoltaics , optoelectronics , conductivity , electrical resistivity and conductivity , voltage , valence band , metal , nanotechnology , electrical engineering , band gap , metallurgy , photovoltaic system , chemistry , crystallography , engineering , catalysis , biochemistry
In article no. 1900192 , Ai Ping Chen, Shuang Yang, Yu Hou, and co‐workers employ a versatile alkaline earth metals doping strategy to engineer the electronic structure of NiO x contacts for inverted planar perovskite solar cells, in which the champion device demonstrates a power conversion efficiency of 19.49% with a high open circuit voltage of 1.14 V. Alkaline earth metals doping can significantly optimize the electrical properties by deepening the valence band maximum and enhancing the hole conductivity.

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