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Simple Strategies for Fabrication of a Periodic Mesoporous Aluminosilicate with Crystalline Walls
Author(s) -
Do Manh Huy,
Wang Tuo,
Cheng Dangguo,
Chen Fengqiu,
Zhan Xiaoli,
Rioux Robert M.,
Gong Jinlong
Publication year - 2014
Publication title -
small
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.785
H-Index - 236
eISSN - 1613-6829
pISSN - 1613-6810
DOI - 10.1002/smll.201401486
Subject(s) - aluminosilicate , mesoporous material , fabrication , materials science , zeolite , nanotechnology , hexagonal crystal system , catalysis , computer science , molecule , simple (philosophy) , phosphonate , chemical engineering , organic chemistry , chemistry , crystallography , medicine , philosophy , alternative medicine , epistemology , pathology , engineering
An alkali‐assisted cooperative assembly process of two different templating systems with aluminosilicate precursors is described. A highly ordered mesoporous zeolite with the 2D hexagonal symmetry mesospores and MFI zeolitic framework walls is synthesized. This method also allows the preparation of ZSM‐5 with c‐ or b‐axis‐aligned mesopores. The materials have promising catalytic activities for organic reactions involving bulky molecules.