Iron Catalyzed Cascade Protocol for the Synthesis of Pyrrolo[1, 2‐ a ]quinoxalines: A Powerful Tool to Access Solid State Emissive Organic Luminophores | Zendy

Lade Jatin J. | Zendy; Patil Bhausaheb N. | Zendy; Sathe Pratima A. | Zendy; Vadagaonkar Kamlesh S. | Zendy; Chetti Prabhakar | Zendy; Chaskar Atul C. | Zendy

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Iron Catalyzed Cascade Protocol for the Synthesis of Pyrrolo[1, 2‐ a ]quinoxalines: A Powerful Tool to Access Solid State Emissive Organic Luminophores

Author(s) -

Lade Jatin J.,

Patil Bhausaheb N.,

Sathe Pratima A.,

Vadagaonkar Kamlesh S.,

Chetti Prabhakar,

Chaskar Atul C.

Publication year - 2017

Publication title -

chemistryselect

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.437

H-Index - 34

ISSN - 2365-6549

DOI - 10.1002/slct.201701383

Subject(s) - quinoxaline , pyrrole , decarboxylation , catalysis , condensation , cascade , combinatorial chemistry , chemistry , oxidative decarboxylation , solid state , organic chemistry , chromatography , physics , thermodynamics

An alluring iron catalyzed cascade process has been developed for the synthesis of pyrrolo[1, 2‐ a ]quinoxalines by using 1‐(2‐aminoaryl)pyrrole and arylacetic acids. This method involves oxidative decarboxylation of arylacetic acids into aromatic aldehydes followed by their condensation with 1‐(2‐aminoaryl)pyrrole. Optical properties of newly synthesized pyrrolo[1, 2‐ a ]quinoxaline derivatives have been systematically investigated in solution as well as in solid state.

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