Premium
Kinetic theory of bridge processes
Author(s) -
Christophorov L. N.,
Gorbach V. V.,
Kharkyanen V. N.
Publication year - 1982
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560220304
Subject(s) - character (mathematics) , kinetic energy , perturbation theory (quantum mechanics) , relaxation (psychology) , polaron , bridge (graph theory) , thermodynamics , perturbation (astronomy) , statistical physics , chemistry , computational chemistry , classical mechanics , physics , mathematics , quantum mechanics , medicine , psychology , social psychology , geometry , electron
The detailed consideration of the kinetic aspect of the bridge process has allowed us to correctly write a kinetic equation beginning with knowledge of system microparameters. The solution of the equations makes it possible to elucidate the character of the relaxation process and to determine its typical constants as functions of those microparameters. Particular attention was given to kinetics in the presence of polaron effects. In this case the standard perturbation theory applied to derive the kinetic equations is not valid. The solutions obtained for this case are different both in the form of correlation functions and in the character of the interaction taken into account.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom