Morphological responses in thermally conditioned linear low density polyethylene

An octene‐modified linear low density polyethylene has been used to examine the mechanisms involved during thermal annealing. Annealing temperatures ranged from 60 to 100°C. Annealing results in crystallinity increments and these respond to two concurrent effects. One involves the segregation from crystalline regions of low molecular weight moieties in the polymer's molecular weight distribution; the other is lamellar thickening, leading to the formation of more highly perfected crystalline domains. In the present polymer, the two effects were found to be in balance at annealing temperatures near 80°C leading to the optimum distribution of crystalline regions in the amorphous portions of the polymer. The effect of thermal conditioning on mechanical properties of the polymer was illustrated in terms of the initial modulus and the polymer's yield strength. The twin mechanisms of molecular fractionation and lamellar thickening were found to influence both of the mechanical property parameters.