Premium
Viscoelastic and mechanical characterization of graphene decorated with graphene quantum dots reinforced epoxy composites
Author(s) -
George Manuel,
Mohanty Akash
Publication year - 2020
Publication title -
polymer engineering and science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.503
H-Index - 111
eISSN - 1548-2634
pISSN - 0032-3888
DOI - 10.1002/pen.25531
Subject(s) - materials science , composite material , epoxy , nanoindentation , graphene , viscoelasticity , ultimate tensile strength , dynamic mechanical analysis , modulus , composite number , dissipation factor , dielectric , polymer , nanotechnology , optoelectronics
Abstract The article explores viscoelastic and mechanical property analysis of graphene decorated with graphene quantum dots (GDGQD) reinforced epoxy composite. Tensile, nanoindentation, and nano‐dynamic mechanical analysis (DMA) tests were conducted on the composite with 0 to 1 wt% filler variation (an interval of 0.25 wt% maintained). The hardness and elastic modulus for two different loading conditions under a frequency range of 10 to 250 Hz were performed. The viscoelastic properties described through loss tangent and storage modulus graphically and the various factors such as modulus and depth of penetration were influenced by force frequency and mobility of the molecular chain. The results revealed the role of GDGQDs as filler material for enhancing the nanomechanical and tensile properties of the epoxy matrix. The differences in the properties can be ascribed to the filler interfacial bonding with the polymer matrix at the molecular level. The macro‐level properties like tensile properties following the same trend as that of the micro‐level properties like nano‐indentation and nano‐DMA results. Further, with the GDGQD aspect ratio, and assuming three‐dimensionally filled randomly orientation of filler, the Halpin‐Tsai model was satisfied with the experimental tensile modulus values.