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Heterocyclic analogues of steroids: VIII —Mass spectrometry of the stereoisomeric derivatives of 8‐aza‐16‐oxaestrane
Author(s) -
Suboch Victor P.,
Lakhvich Fyodor A.,
Liss Leo G.,
Akhrem Affanassi A.
Publication year - 1982
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210170308
Subject(s) - chemistry , mass spectrum , mass spectrometry , metastability , ring (chemistry) , decomposition , ion , resolution (logic) , high resolution , spectral line , fusion , medicinal chemistry , computational chemistry , chromatography , organic chemistry , linguistics , philosophy , artificial intelligence , computer science , physics , astronomy , remote sensing , geology
Abstract Using high resolution mass spectra, metastable ions and selective deuteration the decomposition pathways of 8‐aza‐16‐oxasteroid derivatives have been investigated. There is a dependence of the mass spectra on the stereochemistry of the C/D ring fusion in 8‐aza‐16‐oxaestrane derivatives.