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Behaviour of the high‐frequency component of the OH stretching Raman band of water in H 2 O 2 H 2 O mixtures
Author(s) -
Zhelyaskov V.,
Georgiev G.,
Nickolov Zh.,
Miteva N.
Publication year - 1990
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250210308
Subject(s) - raman spectroscopy , component (thermodynamics) , deconvolution , fourier transform , chemistry , analytical chemistry (journal) , low frequency , spectral line , hydrogen bond , molecule , thermodynamics , optics , physics , chromatography , organic chemistry , quantum mechanics , astronomy
Abstract The Fourier deconvolution technique was applied to the analysis of Raman OH stretching spectra in H 2 O 2 H 2 O mixtures. An intensity decrease and a low‐frequency shift of the resolved high‐frequency component at 3635 cm −1 was established and can be used in the elucidation of physical models explaining the existence of weakly hydrogen‐bonded OH oscillators in liquid water.