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Rotation‐vibrational bands of gaseous allene‐ d 4
Author(s) -
Andersen Helge Blom,
Hegelund Flemming,
Zangenberg Nina Rothe,
Winther Flemming
Publication year - 1977
Publication title -
journal of raman spectroscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.748
H-Index - 110
eISSN - 1097-4555
pISSN - 0377-0486
DOI - 10.1002/jrs.1250060506
Subject(s) - allene , yield (engineering) , chemistry , rotation (mathematics) , raman spectroscopy , perpendicular , atomic physics , analytical chemistry (journal) , nuclear magnetic resonance , physics , optics , geometry , mathematics , organic chemistry , thermodynamics , catalysis
Abstract Many of the fundamental bands of allene‐ d 4 have been analysed to yield a number of molecular constants, including the ground state constants A o — B o = 2.1832 ± 0.0004 cm −1 and D ko = (2.8 ± 0.2) × 10 −5 cm −1 . A reassignment of the perpendicular bands ν 8 and ν 11 is proposed.