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Synthesis of antheridiol‐(22,23‐ 3 H)
Author(s) -
McMorris Trevor C.,
Arunachalam Thangavel
Publication year - 1975
Publication title -
journal of labelled compounds
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0022-2135
DOI - 10.1002/jlcr.2590110413
Subject(s) - radiochemistry , chemistry , physics
Abstract Antheridiol‐(22,23‐ 3 H) has been prepared by reduction of 3‐acetoxy‐23,23‐dihydroxy‐22‐oxo‐5, 24(28)‐ergostadiene‐28‐carboxylic acid gamma ‐ lactone with tritiated sodium borohydride followed by hydrolysis, photo‐oxygenation and cupric chloride catalysed rearrangement.