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Carboxyl group ‐CO 2 exchange in the thermal decomposition of aliphatic dicarboxylic acid salts
Author(s) -
Szabolcs A.,
Szammer J.
Publication year - 1974
Publication title -
journal of labelled compounds
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0022-2135
DOI - 10.1002/jlcr.2590100113
Subject(s) - thermal decomposition , dicarboxylic acid , decomposition , chemistry , carbon dioxide , ion exchange resin , group (periodic table) , ion exchange , inorganic chemistry , organic chemistry , polymer chemistry , ion
The exchange reaction of carboxyl groups with carbon dioxide has been studied in thermal decomposition of aliphatic dicarboxylic acid disodium salts. It has been found that exchange takes place under given experimental conditions. In some cases the process results in considerable exchange even in lower conversion ranges therefore it is of significance in the field of isotopes techniques.