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The oxidative cleavage of amines by iodine monochloride
Author(s) -
Ghaffari M. A.,
Ali H.,
Van Lier J. E.
Publication year - 1989
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580270116
Subject(s) - iodine monochloride , chemistry , oxidative cleavage , halogenation , iodine , cleavage (geology) , oxidative phosphorylation , organic chemistry , medicinal chemistry , catalysis , biochemistry , geotechnical engineering , fracture (geology) , engineering
The formation of secondary products during the radioiodination of aromatic amines is reported. Iodination of a series of N,N‐dimethyl‐N'‐(alkylphenyl)‐1,3‐propanediamines with IC1 in the presence of AcOH and HClO 4 gave in addition to the expected iodo derivatives substantially amounts of secondary cleavage products which were identified as the corresponding iodobenzaldehyde derivatives.