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Syntheses with stable isotopes: Acetic‐1‐ 13 C,‐2‐ 13 C,‐ 13 C 2 , and ‐ 12 C 2 acids
Author(s) -
Ott Donald G.,
Kerr Ver N.
Publication year - 1976
Publication title -
journal of labelled compounds and radiopharmaceuticals
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.432
H-Index - 47
eISSN - 1099-1344
pISSN - 0362-4803
DOI - 10.1002/jlcr.2580120114
Subject(s) - chemistry , carbon 13 , acetic acid , methanol , isotope , carbonylation , kinetic isotope effect , rhodium , stable isotope ratio , carbon 14 , isotopes of carbon , radiochemistry , oxygen 18 , carbon monoxide , catalysis , deuterium , nuclear chemistry , organic chemistry , nuclear physics , physics , total organic carbon , isotopes of oxygen
Rhodium‐catalyzed carbonylation of methanol at mild temperature and pressure has been developed for small‐ and large‐scale preparations of the carbon isotope isomers of acetic acid.