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Stereoselective Synthesis of Alcohols, XLIII. Asymmetric Induction on the Intramolecular Allylboration Reaction of (8‐Oxo‐2‐octenyl)boronates
Author(s) -
Hoffmann Reinhard W.,
Sander Thomas
Publication year - 1993
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.1993199301192
Subject(s) - chemistry , intramolecular force , stereoselectivity , asymmetric induction , stereochemistry , organic chemistry , enantioselective synthesis , catalysis
The cyclization of (8‐oxo‐2‐octenyl)boronates having methyl substituents in the chain linking the two functional groups proceeds with complete simple diastereoselectivity and with induced diastereoselectivity of 85 to > 98% to give methylsubstituted 2‐vinylcyclohexanols.