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Synthesis of sphingosine relatives, X. Synthesis of (2 S ,3 R 4 E )‐1‐ O ‐(β‐ D ‐glucopyranosyl)‐ N ‐[30′‐(linoleoyloxy)triacontanoyl]‐4‐icosasphingenine, a new esterified cerebroside isolated from human and pig epidermis
Author(s) -
Mori Kenji,
Matsuda Hiroyuki
Publication year - 1991
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.199119910197
Subject(s) - chemistry , cerebroside , sphingosine , stereochemistry , linoleic acid , ceramide , biochemistry , fatty acid , apoptosis , receptor
(2 S ,3 R ,4 E )‐1‐ O ‐(β‐ D ‐Glucopyranosyl)‐ N ‐[30′‐(linoleoyloxy)triacontanoyl]‐4‐icosasphingenine ( 1 ) was synthesized from D ‐glucose, L ‐serine, 15‐pentadecanolide, and linoleic acid. The high‐field 1 H‐NMR spectrum of 1 was identical with that of the esterified cerebroside isolated from human and pig epidermis.