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Facile Reductive Cleavage of Oximes with a Low‐Valent Titanium Reagent
Author(s) -
Balicki Roman,
Kaczmarek Lukasz,
Malinowski Marek
Publication year - 1989
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198919890283
Subject(s) - chemistry , reagent , oxidative cleavage , cleavage (geology) , titanium , oxime , combinatorial chemistry , organic chemistry , catalysis , geotechnical engineering , fracture (geology) , engineering
The application of the TiCl 4 /SnCl 2 reagent system in the reductive deoximation of various ketoximes and aldoximes under mild conditions is reported. The corresponding carbonyl compounds were formed in high yields.