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Oxidation of Organic Diselenides with Hydrogen Peroxide to Alkane‐ and Areneseleninic Acids and Selenium‐Containing Heterocycles
Author(s) -
Kloc Krystian,
Mlochowski Jacek,
Syper Ludwik
Publication year - 1989
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198919890229
Subject(s) - chemistry , selenium , hydrogen peroxide , alkane , organic chemistry , peroxide , catalysis
A convenient way is reported for the oxidation of organic diselenides 1, 3 to organoseleninic acids 2, 4 which were isolated and identified as pure compounds. Some ortho ‐substituted phenyl diselenides 3d–f underwent oxidative cyclization, and the selenium‐containing heterocyclic compounds 5 were obtained.