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Insect Growth Regulators, 24. Synthesis of Optically Active, Branched Juvenoids
Author(s) -
Wawrzeńczyk Czeslaw,
Zabża Andrzej,
Aniol Miroslaw
Publication year - 1989
Publication title -
liebigs annalen der chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 0170-2041
DOI - 10.1002/jlac.198919890103
Subject(s) - geraniol , chemistry , enantioselective synthesis , optically active , enantiomer , alcohol , stereochemistry , combinatorial chemistry , organic chemistry , chromatography , essential oil , catalysis
Starting from geraniol ( 3 ), the synthesis of both enantiomers of the branched juvenoids 1a,b is described. Resolution of the racemic mixture of alcohol 4a was performed by Sharpless enantioselective epoxidation.