Basic Ionic Liquid as Catalyst and Reaction Media for the One‐pot Three‐component  Regioselective Synthesis  of Various Thiazol‐2‐imine Derivatives | Zendy

Shiran Jafar Abbasi | Zendy; Yahyazadeh Asieh | Zendy; Yamin Bohari M. | Zendy; Mamaghani Manouchehr | Zendy; Albadi Jalal | Zendy

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Basic Ionic Liquid as Catalyst and Reaction Media for the One‐pot Three‐component Regioselective Synthesis of Various Thiazol‐2‐imine Derivatives

Author(s) -

Shiran Jafar Abbasi,

Yahyazadeh Asieh,

Yamin Bohari M.,

Mamaghani Manouchehr,

Albadi Jalal

Publication year - 2016

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.2406

Subject(s) - chemistry , regioselectivity , imine , catalysis , ionic liquid , amine gas treating , combinatorial chemistry , aryl , ionic bonding , organic chemistry , component (thermodynamics) , reaction conditions , ion , alkyl , physics , thermodynamics

Thiazol‐2‐imine derivatives were synthesized in an easy and efficient route from the regioselective one‐pot three‐component reaction of aryl amine, alkylisothiocyanate, and various α‐haloketones in [omim][OH] basic ionic liquid. Recyclable reaction media, catalyst free, and short reaction times are the main advantages of this protocol. This method produces the products at room temperature in excellent yields (68–96%). Furthermore, the target compound 6b was determined by X‐ray crystallographic analysis.

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