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Diverse Modes of Reactivity of 6‐(Chloromethyl)‐6‐methylfulvene
Author(s) -
Erden Ihsan,
Gronert Scott,
Cabrera Gabriel,
Coskun Necdet,
Tapken Marco
Publication year - 2017
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201700442
Subject(s) - nucleophile , chemistry , electrophile , reactivity (psychology) , enamine , stereochemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
The title compound exhibits a number of modes of reactivity toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6‐(chloromethyl)‐6‐methylfulvene with oxygen and nitrogen nucleophiles and bases as well as a carbon‐based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound.

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