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Studies towards the Synthesis of Pentalenene: Mechanistic Insights into the Isomerization Phenomenon During RCM of Medium‐Sized Rings
Author(s) -
De Bo Guillaume,
Markó István E.
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001475
Subject(s) - isomerization , chemistry , ring closing metathesis , metathesis , perspective (graphical) , mechanism (biology) , salt metathesis reaction , combinatorial chemistry , organic chemistry , catalysis , computer science , epistemology , philosophy , polymer , artificial intelligence , polymerization
Isomerization issues have been encountered during the ring‐closing metathesis (RCM) step of a new approach towards pentalenene. This paper describes the mechanistic insights gained during the study of this side reaction from a substrate perspective. Isomerization issues have been encountered during the RCM step of a new approach towards pentalenene.
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