2,6‐Disubstituted Tetrahydropyrans by Tandem Cross‐Metathesis/Iodocyclisation | Zendy

Hiebel MarieAude | Zendy; Pelotier Béatrice | Zendy; Goekjian Peter | Zendy; Piva Olivier | Zendy

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2,6‐Disubstituted Tetrahydropyrans by Tandem Cross‐Metathesis/Iodocyclisation

Author(s) -

Hiebel MarieAude,

Pelotier Béatrice,

Goekjian Peter,

Piva Olivier

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200700902

Subject(s) - tetrahydropyran , chemistry , metathesis , tandem , salt metathesis reaction , sequence (biology) , stereochemistry , combinatorial chemistry , organic chemistry , ring (chemistry) , polymerization , biochemistry , materials science , composite material , polymer

A new approach to 2,6‐disubstituted tetrahydropyrans by a tandem cross‐metathesis/iodocyclisation reaction has been developed. The stereochemical outcome of the cyclisation reactions has been studied for different substrates. This sequence has allowed the preparation of a series of cis ‐ and trans ‐2,6‐disubstituted analogues of the tetrahydropyran subunit of bistramide A.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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