A Structural and Magnetic Investigation of Ferromagnetically Coupled Copper( II ) Isophthalates (Eur. J. Inorg. Chem. 12/2005)
Author(s) -
Shen WeiZheng,
Chen XiaoYan,
Chen Peng,
Yan ShiPing,
Zhai Bin,
Liao DaiZheng,
Jiang ZongHui
Publication year - 2005
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200590026
Subject(s) - chemistry , denticity , ligand (biochemistry) , crystallography , copper , ferromagnetism , cover (algebra) , stereochemistry , crystal structure , receptor , condensed matter physics , organic chemistry , physics , mechanical engineering , biochemistry , engineering
Abstract The cover picture shows how the isophthalate‐bridged jystructures are tuned by various polydentate ligands from tetradentate ligand tpa to tridentate ligand tpm to bidentate ligand bpm, which results in one dinuclear and two one‐dimensional complexes, [Cu 2 (tpa) 2 ( m ‐bda)](ClO 4 ) 2 ( 1 ), {[Cu 2 (tpm) 2 ( m ‐bda) 2 ]·2CH 3 OH·4H 2 O} n ( 2 ) and {[Cu 2 (bpm) 2 ( m ‐bda) 2 (H 2 O)]·CH 3 CN·H 2 O} n ( 3 ). The variable‐temperature magnetic behavior reveals the existence of ferromagnetic interactions in them. Details of synthesis and characterization of these complexes are given in the article by P. Cheng et al. on p. 2297 ff.