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Cure kinetics characterization of soy‐based epoxy resins for infusion moulding process
Author(s) -
Subbiah Rajkumar,
Tjong Jimi,
Nayak Sanjay K.,
Sain Mohini
Publication year - 2016
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.22504
Subject(s) - epoxy , diglycidyl ether , kinetics , differential scanning calorimetry , materials science , bisphenol a , isothermal process , enthalpy , ultimate tensile strength , composite material , chemical engineering , polymer chemistry , thermodynamics , physics , quantum mechanics , engineering
This study presents the kinetics of the reaction of diglycidyl ether of bisphenol A (DGEBA) based epoxy resin in the presence of epoxidized soybean oil (ESO) cured with triethylene tetramine (TETA). An isothermal differential scanning calorimetric (DSC) study is carried out to propose a model to analyze the cure kinetics of bio‐based resin. The proposed model is also compared with the Kamal model. The results clearly highlight that the proposed model attains a reasonable percentage of improvement in predicting cure data. Adding ESO to the conventional system decreases the reaction enthalpy and increases the activation energy of the system. The outcome of the study confirms the feasibility of the proposed material system for an infusion process. Further, tensile property improvement is obtained through using an infusion process for the proposed material system.
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