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Cover Feature: Heterobimetallic Gold/Ruthenium Complexes Synthesized via Post‐functionalization and Applied in Dual Photoredox Gold Catalysis (Chem. Eur. J. 57/2022)
Author(s) -
Bayer Lea,
Birenheide Bernhard S.,
Krämer Felix,
Lebedkin Sergei,
Breher Frank
Publication year - 2022
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202202777
Subject(s) - ruthenium , surface modification , catalysis , cover (algebra) , combinatorial chemistry , chemistry , dual (grammatical number) , photochemistry , polymer chemistry , organic chemistry , art , engineering , mechanical engineering , literature
Enjoying the sun : The cover illustrates the potential of heterobimetallic Au I /Ru II complexes to facilitate the P arylation of H‐phosphonates with diazonium salts, while visible light kicks off the dual gold and photoredox catalytic cycle. The underlying structure of the catalysts’ coordinating ligand system is accessible by a novel postfunctionalization approach, and the stereochemistry can be controlled by the order of metal coordination and click reaction. More information can be found in the Research Article by F. Breher and co‐workers (DOI: 10.1002/chem.202201856).