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Reusable Manganese Catalyst for Site‐Selective Pyridine C−H Arylations and Alkylations
Author(s) -
Choi Isaac,
Shen Zhigao,
Ronge Emanuel,
Karius Volker,
Jooss Christian,
Ackermann Lutz
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202101894
Subject(s) - manganese , pyridine , catalysis , chemistry , combinatorial chemistry , organic chemistry
Abstract Herein, we disclose a recyclable, hybrid manganese catalyst for site‐selective azine C−H activation by weak amide assistance. The novel, reusable catalyst enabled C3–H arylation and C3–H alkylation with ample scope, and was characterized by detailed transmission electron microscopy analysis.