Frontispiece: Engineering Metal–Organic Framework Catalysts for C−C and C−X Coupling Reactions: Advances in Reticular Approaches from 2014–2018 | Zendy

Kousik Shravan | Zendy; Velmathi Sivan | Zendy

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Frontispiece: Engineering Metal–Organic Framework Catalysts for C−C and C−X Coupling Reactions: Advances in Reticular Approaches from 2014–2018

Author(s) -

Kousik Shravan,

Velmathi Sivan

Publication year - 2019

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201987262

Subject(s) - metal organic framework , reticular connective tissue , catalysis , metal , porosity , ligand (biochemistry) , materials science , scaffold , nanotechnology , chemistry , denticity , organic chemistry , computer science , adsorption , medicine , biochemistry , receptor , pathology , database

A typical MOF consists of a three‐dimensional matrix of metal ions stabilized by ligating polydentate organic linkers. A characteristic structural feature of MOFs is the presence of porous labyrinthine channels within the core metal–ligand scaffold. In their Review on page 16451 ff., S. Kousik and S. Velmathi explore the use of metal–organic frameworks (MOFs) in C−C, C−N, and C−O coupling reactions reported between 2014 and 2018. The influence of pore size, pore environment, and load on catalytic activity is described. Post‐synthetic stabilization techniques and host–guest interactions in caged MOF scaffolds are detailed. Mechanistic aspects pertaining to the use of MOFs in asymmetric heterogeneous catalysis are highlighted and categorized.

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