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Boron Clusters as a Platform for New Materials: Synthesis of Functionalized o ‐Carborane (C 2 B 10 H 12 ) Derivatives Incorporating DNA Fragments
Author(s) -
Janczak Slawomir,
Olejniczak Agnieszka,
Balabańska Sandra,
Chmielewski Marcin K.,
Lupu Marius,
Viñas Clara,
Lesnikowski Zbigniew J.
Publication year - 2015
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201502822
Subject(s) - carborane , boron , chemistry , crystallography , stereochemistry , organic chemistry
A synthetic strategy for functionalization of the three vertices of o ‐carborane and the attachment of the obtained triped to the solid support was developed. Further functionalization of the triped with short DNA sequences by automated DNA synthesis was achieved. The proposed methodology is a first example of boron cluster chemistry on a solid support opening new perspectives in boron cluster functionalization.
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