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Formation of Ti 28 Ln Cages, the Highest Nuclearity Polyoxotitanates (Ln=La, Ce)
Author(s) -
Lv Yaokang,
Willkomm Janina,
Leskes Michal,
Steiner Alexander,
King Timothy C.,
Gan Lihua,
Reisner Erwin,
Wood Paul T.,
Wright Dominic S.
Publication year - 2012
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201201827
Subject(s) - crystallography , ion , materials science , lanthanide , chemistry , organic chemistry
The solvothermal reactions of Ti(OEt) 4 with LnCl 3 (Ln=La, Ce) produced new Ti 28 Ln cages, in which the Ln 3+ ions are coordinated within a metallocrown arrangement, which represents the highest nuclearity cages of this type (see figure).
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