1,7‐Octadiene‐Assisted Tandem Multicomponent Cross‐Enyne Metathesis (CEYM)‐Diels–Alder Reactions: A Useful Alternative to Mori’s Conditions | Zendy

Fustero Santos | Zendy; Bello Paula | Zendy; Miró Javier | Zendy; Simón Antonio | Zendy; del Pozo Carlos | Zendy

Premium

1,7‐Octadiene‐Assisted Tandem Multicomponent Cross‐Enyne Metathesis (CEYM)‐Diels–Alder Reactions: A Useful Alternative to Mori’s Conditions

Author(s) -

Fustero Santos,

Bello Paula,

Miró Javier,

Simón Antonio,

del Pozo Carlos

Publication year - 2012

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201200835

Subject(s) - enyne metathesis , tandem , metathesis , ethylene , diels–alder reaction , chemistry , salt metathesis reaction , enyne , organic chemistry , combinatorial chemistry , materials science , catalysis , polymerization , composite material , polymer

The use of 1,7‐octadiene as an in situ source of ethylene led us to develop a novel multicomponent tandem cross‐enyne metathesis (CEYM)‐Diels–Alder reaction. The process can be considered a relay metathesis, in which the ethylene liberated in the ring‐closing metathesis (RCM) of 1,7‐octadiene initiates the tandem sequence. Aliphatic, aromatic, and fluorinated alkynes and several dienophiles are compatible with the process, which is particularly efficient with aromatic alkynes. This methodology constitutes a useful variant of Mori’s conditions in CEYM‐related reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research