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A General Approach for the Growth of Metal Oxide Nanorod Arrays on Graphene Sheets and Their Applications
Author(s) -
Zou Rujia,
Zhang Zhenyu,
Yu Li,
Tian Qiwei,
Chen Zhigang,
Hu Junqing
Publication year - 2011
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201101981
Subject(s) - nanorod , materials science , photocatalysis , graphene , heterojunction , nanotechnology , oxide , nanocrystal , nanoscopic scale , hydrothermal circulation , fabrication , metal , semiconductor , chemical engineering , rutile , optoelectronics , metallurgy , chemistry , medicine , biochemistry , alternative medicine , pathology , engineering , catalysis
Abstract In the fabrication of flexible devices, highly ordered nanoscale texturing, such as semiconductor metal oxide nanorod arrays on flexible substrates, is critical for optimal performance. Use of transparent conducting films, metallic films, and polymer substrates is limited by mechanical brittleness, chemical and thermal instability, or low electrical conductivity, low melting point, and so on. A simple and general nanocrystal‐seed‐directed hydrothermal route has now been developed for large‐scale growth of nanorod arrays of various semiconductor metal oxides (MO), including TiO 2 , ZnO, MnO 2 , CuO, and ZrO 2 on both sides of flexible graphene (G) sheets to form sandwichlike MO/G/MO heterostructures. The TiO 2 /G/TiO 2 heterostructures have much higher photocatalytic activity than TiO 2 nanorods, with a photocatalytic degradation rate of methylene blue that is four times faster than that of the TiO 2 nanorods, and are thus promising candidates for photocatalytic decontamination.