A New Entry into Aluminum Chemistry: [L 1 AlMe]⋅THF, a Versatile Building Block for Bimetallic and Polymetallic Complexes | Zendy

Sarish Sankaranarayana Pillai | Zendy; Nekoueishahraki Bijan | Zendy; Jana Anukul | Zendy; Roesky Herbert W. | Zendy; Schulz Thomas | Zendy; Stalke Dietmar | Zendy

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A New Entry into Aluminum Chemistry: [L 1 AlMe]⋅THF, a Versatile Building Block for Bimetallic and Polymetallic Complexes

Author(s) -

Sarish Sankaranarayana Pillai,

Nekoueishahraki Bijan,

Jana Anukul,

Roesky Herbert W.,

Schulz Thomas,

Stalke Dietmar

Publication year - 2011

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001809

Subject(s) - bimetallic strip , chemistry , tin , bismuth , amide , reactivity (psychology) , zinc , chloride , medicinal chemistry , metal , nuclear magnetic resonance spectroscopy , nuclear chemistry , stereochemistry , organic chemistry , medicine , alternative medicine , pathology

[L 1 AlMe]⋅THF ( 1 ; L 1 =CH[C(CH 2 )](CMe)(2,6‐ i Pr 2 C 6 H 3 N) 2 ) is prepared by a new method to test its reactivity towards metal complexes to give heterobimetallic or polymetallic complexes. The treatment of 1 with germanium chloride ([LGeCl]), tin chloride ([LSnCl]; L=CH(CMe2,6‐ i Pr 2 C 6 H 3 N) 2 ), bismuth amide ([1,8‐C 10 H 6 (NSiMe 3 ) 2 BiNMe 2 ]), and dimethyl zinc (ZnMe 2 ) gave the desired compounds with different functional groups on the aluminum center. All compounds have been thoroughly characterized by multinuclear NMR spectroscopy, EI mass spectrometry, X‐ray crystallography ( 2 , 3 , and 5 ), and elemental analysis.

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