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Synthesis and Characterization of Novel Octakis(2′‐aminophenoxy and 2′‐Aminophenylsulfanyl)‐Substituted Metallophthalocyanines
Author(s) -
Kandaz Mehmet,
Bekaro.Lu özer
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971301220
Subject(s) - chemistry , anhydrous , phthalocyanine , metal , stereochemistry , medicinal chemistry , organic chemistry
Abstract Novel phthalocyanines (M = Ni, Zn, Co) bearing eight 2′‐aminophenoxy and 2′‐amino phenylsulfanyl substitutents on peripheral positions have been prepared starting from 4,5‐bis(2′‐aminophnoxy)−1,2‐dicyanobenzene and the corresponding anhydrous metal salts [NiCl 2 , Zn(O 2 CMe) 2 , CoCl 2 ]‐ Complexation of octakis(2′‐amino phenylsulfanyl)‐substituted metallo phthalocyanines ( 2b, 3b and 4b ) with Pd 11 to form the pentanuclear product was accomplished from their mixtures.