Synthese und Röntgenstrukturanalyse einer neuartigen gemischtvalenten zwitterionischen Diphosphor‐Fluor‐Verbindung | Zendy

Dunmur Richard E. | Zendy; Thönnessen Holger | Zendy; Müller Christian | Zendy; Farkens Michael | Zendy; Fischer Axel | Zendy; Jones Peter G. | Zendy; Schmutzler Reinhard | Zendy

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Synthese und Röntgenstrukturanalyse einer neuartigen gemischtvalenten zwitterionischen Diphosphor‐Fluor‐Verbindung

Author(s) -

Dunmur Richard E.,

Thönnessen Holger,

Müller Christian,

Farkens Michael,

Fischer Axel,

Jones Peter G.,

Schmutzler Reinhard

Publication year - 1993

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19931261214

Subject(s) - chemistry , crystal structure , nuclear magnetic resonance spectroscopy , mass spectrometry , crystallography , biuret test , spectroscopy , infrared spectroscopy , single crystal , stereochemistry , molecule , organic chemistry , physics , urea , chromatography , quantum mechanics

Synthesis and X‐Ray Crystal Structure Analysis of a Novel Mixed‐Valent Zwitterionic Diphosphorus Fluoro Compound The cyclic zwitterionic λ 6 P,λ 4 P‐diphosphorus compound F 5 P – N(Me)P + [N(Me)C(=O)] 2 NMe ( 3 ), which contains a biuret system, was synthesized by the reaction of (MeNPF 3 ) 2 ( 1 ) with MeNCO ( 2 ). Compound 3 was characterized by means of 1 H‐, 13 C‐, 19 F‐ and 31 P‐NMR spectroscopy, IR spectroscopy, and mass spectrometry. A single‐crystal X‐ray structure determination revealed the presence of two independent formula units, in which the –N(Me)PF 5 side chains display widely differing conformations.

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