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Electrochemical Detection of 2‐Nitrophenol Using a Glassy Carbon Electrode Modified with BaO Nanorods
Author(s) -
Alam M. M.,
Asiri Abdullah M.,
Rahman Mohammed M.
Publication year - 2021
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.202100250
Subject(s) - detection limit , nanorod , differential pulse voltammetry , x ray photoelectron spectroscopy , analytical chemistry (journal) , materials science , calibration curve , electrochemical gas sensor , electrode , electrochemistry , cyclic voltammetry , nanomaterials , chemistry , nanotechnology , chemical engineering , chromatography , engineering
Abstract Here, an electrochemical detection approach (differential pulse voltammetry) was employed to develop a 2‐nitrophenol (2‐NP) sensor probe using a glassy carbon electrode (GCE) coated by wet‐chemically synthesized nanorods (NRs) of BaO. The prepared BaO NRs were characterized by field‐emission scanning electron microscopy (FESEM), energy‐dispersive X‐ray spectroscopy (EDS), X‐ray photoelectron spectroscopy (XPS) and powder X‐ray diffraction (XRD) analysis. The peak currents by differential pulse voltammetric (DPV) analysis of 2‐NP are plotted against the concentration to obtain the calibration curve of the 2‐NP detection. It was found to be linear from 1.5 to 9.0 μM, defined as the dynamic range (LDR) for 2‐NP detection in phosphate buffer solution. The sensor sensitivity was calculated from the slope of LDR by considering the active surface area of NRs coated on GCE (0.0316 cm 2 ) and found as 17.6 μAμM −1 cm −2 . The limit of detection (LOD) was calculated as 0.50±0.025 μM from the signal/noise (S/N) ratio of 3. Moreover, the sensor analytical parameters such as reproducibility, long‐term performing ability (stability), response time and validity in real environmental samples were found acceptable and to give satisfactory results. The development of a nanomaterial‐based electrochemical chemical sensor might be an effective approach to sensor technology to detect carcinogenic and hazardous toxins for environmental safety and healthcare fields in a broad scale.