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Synthesis of alkyne‐terminated xanthate RAFT agents and their uses for the controlled radical polymerization of N ‐vinylpyrrolidone and the synthesis of its block copolymer using click chemistry
Author(s) -
Patel Vijay Kumar,
Vishwakarma Niraj Kumar,
Mishra Avnish Kumar,
Biswas Chandra Sekhar,
Maiti Pralay,
Ray Biswajit
Publication year - 2012
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.38037
Subject(s) - chain transfer , polymer chemistry , xanthate , reversible addition−fragmentation chain transfer polymerization , copolymer , polymerization , radical polymerization , monomer , living polymerization , living free radical polymerization , chemistry , dispersity , raft , polymer , materials science , organic chemistry
Abstract Two new alkyne‐terminated xanthate reversible addition‐fragmentation chain‐transfer (RAFT) agents: ( S )‐2‐(Propynyl propionate)‐( O ‐ethyl xanthate) (X 3 ) and ( S )‐2‐(Propynyl isobutyrate)‐( O ‐ethyl xanthate) (X 4 ) were synthesized and characterized and used for the controlled radical polymerization of N ‐vinylpyrrolidone (NVP). X 3 showed better chain transfer ability in the polymerization at 60°C. Molecular weight of the resulted polymer increased linearly with the increase in monomer loading. Kinetics study with X 3 showed the pseudo‐first order kinetics up to 67% monomer conversion. Molecular weight ( M n ) of the resulting polymer increased linearly with the increase in the monomer conversion up to around 67%. With the increase in the monomer conversion, polydispersity of the corresponding poly(NVP)s initially decreased from 1.34 to 1.32 and then increased gradually to 1.58. Chain‐end analysis of the resulting polymer by 1 H‐NMR and FTIR showed clearly that polymerization started with radical forming out of xanthate RAFT agent. Living nature of the polymerization was also confirmed from the successful homo‐chain extension experiment and the hetero‐chain extension experiment involving synthesis of poly(NVP)‐ b ‐polystyrene amphiphilic diblock copolymer. Formed alkyne‐terminated poly(NVP) also allowed easy conjugation to azide‐terminated polystyrene by click chemistry to prepare well‐defined poly(NVP)‐ b ‐polystyrene block copolymers. Resulting polymers were characterized by GPC, 1 H‐NMR, FTIR, and thermal study. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013