Inside Back Cover: Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. Int. Ed. 47/2019) | Zendy

Wu ZhengJian | Zendy; Su Feng | Zendy; Lin Weidong | Zendy; Song Jinshuai | Zendy; Wen TingBin | Zendy; Zhang HuiJun | Zendy; Xu HaiChao | Zendy

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Inside Back Cover: Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. Int. Ed. 47/2019)

Author(s) -

Wu ZhengJian,

Su Feng,

Lin Weidong,

Song Jinshuai,

Wen TingBin,

Zhang HuiJun,

Xu HaiChao

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201912601

Subject(s) - rhodium , electrosynthesis , catalytic cycle , reductive elimination , aryl , chemistry , catalysis , anode , anodic oxidation , redox , oxidation state , combinatorial chemistry , electrochemistry , organic chemistry , electrode , alkyl

Electrochemically driven rhodium(III)‐catalyzed aryl C–H phosphorylation reactions proceed by H 2 evolution without the need for sacrificial chemical oxidants, as described by T.‐B. Wen, H.‐J. Zhang, H.‐C. Xu, and co‐workers in their Communication on page 16770 ff. A key step of the electrosynthesis involves anodic oxidation of a rhoda(III)cycle to a higher oxidation state to induce reductive elimination. The design illustrates electrifying the Rh center of a key organometallic complex in the catalytic cycle.

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