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Screening of Metal Borohydrides by Mechanochemistry and Diffraction
Author(s) -
Ravnsbæk Dorthe B.,
Sørensen Lise H.,
Filinchuk Yaroslav,
Besenbacher Flemming,
Jensen Torben R.
Publication year - 2012
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201106661
Subject(s) - mechanochemistry , diffraction , decomposition , metal , x ray crystallography , materials science , cadmium , chemical engineering , chemistry , nanotechnology , crystallography , metallurgy , organic chemistry , engineering , optics , physics
Ay, there's the rub : The formation of cadmium‐based borohydrides is screened by mechanochemical synthesis using various reactants in different ratios. Sequential in situ variable‐temperature diffraction studies provide simultaneous information about composition, structure, decomposition pathways, and properties of the compounds.
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